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The solute carbon content in ferrite is one of the important factors to obtain good formability in low carbon steels. Although most of the carbons are consumed by the formation of grain boundary cementite during coiling after hot-rolling, the carbon content after coiling is normally observed much more than that of equilibrium. In this study, a classical nucleation and growth model is used to simulate the precipitation kinetics of the grain boundary cementite from coiling temperature (CT) to room temperature (RT). The predicted precipitation behaviors depending on the initial carbon content and the cooling rate are compared with the reported. As a result, the lateral growth of thickening of cementite is a major factor for the sluggish reaction of grain boundary cementite. The reduction of solute carbon content after coiling is divided into three regions: a) increase due to no cementite precipitation, b) decrease due to the fast length-wise growth of cementite, c) increase due to the slow thickness-wise growth of cementite.

keyword : alloy, thermomechanical processing, precipitation, computer simulation, solute carbon content

Application of a stronger and more durable material for reactor pressure vessels (RPVs) might be an effective way to insure the integrity and increase the efficiency of nuclear power plants. A series of research projects to apply the SA508 Gr.4 steel in ASME code to RPVs are in progress because of its excellent strength and durability compared to commercial RPV steel (SA508 Gr.3 steel). In this study, the microstructural characteristics and mechanical properties of SA508 Gr.3 Mn-Mo-Ni low alloy steel and SA508 Gr.4N Ni-Mo-Cr low alloy steel were investigated. The differences in the stable phases between these two low alloy steels were evaluated by means of a thermodynamic calculation using ThermoCalc. They were then compared to microstructural features and correlated with mechanical properties. Mn-Mo-Ni low alloy steel shows the upper bainite structure that has coarse cementite in the lath boundaries. However, Ni-Mo-Cr low alloy steel shows the mixture of lower bainite and tempered martensite structure that homogeneously precipitates the small carbides such as M23C6 and M7C3 due to an increase of hardenability and Cr addition. In the mechanical properties, Ni-Mo-Cr low alloy steel has higher strength and toughness than Mn-Mo-Ni low alloy steel. Ni and Cr additions increase the strength by solid solution hardening. In addition, microstructural changes from upper bainite to tempered martensite improve the strength of the low alloy steel by grain refining effect, and the changes in the precipitation behavior by Cr addition improve the ductile-brittle transition behavior along with a toughening effect of Ni addition.

keyword : alloy, forging, mechanical properties, impact test, reactor pressure vessel

An application of the instrumented indentation technique has been expanded from the measurements of hardness and elastic modulus to the analysis of residual stress. A slope of the indentation loading curve increases (or decreases) according to compressive (or tensile) residual stress. A theoretical equation has been established for quantifying residual stress from the slope change. However, a precise observation of the remnant indents is indispensible because the theoretical approach needs actual contact information. In addition, the conventional hardness test is still used for predicting the residual stress distribution of welded joints. Thus, we observed the three-dimensional morphologies of the remnant indents formed on artificial stress states and analyzed stress effects on morphological recovery of the indents. First, a depth recovery ratio, which has been regarded as a sensitive stress indicator, did not show a clear dependency with the residual stress. Thus an analysis on volumetric recovery was tried in this study and yielded a inverse proportional behavior with the residual stress. In addition, an elastic to plastic volume recovery ratio showed more significant correlation with the residual stress.

keyword : amorphous materials, deformation, residual stress, indentation, image analysis

The effects of cooling rate and onset time of fatigue test on hot ductility of plain carbon steels containing 0.06~0.8 wt.% carbon were investigated at various temperatures. The tensile tested specimen after fatigue strain during cooling showed higher hot ductility than the specimen fatigued and tensile-strained after cooling. With a decreasing cooling rate from solutionizing temperature to test temperature, hot ductility was increased in all temperature ranges, typically in the trough region, and the minimum point of ductility moved to a lower temperature. Also, the depth and width of the trough decreased with lowering the cooling rate.

keyword : metals, thermomechanical processing, fatigue, tensile test, hot ductility

Direct copper electroplating on Mg alloy AZ31B was carried out in a traditional pyrophosphate copper bath containing potassium fluoride. Electrochemical impedance spectroscopy and polarization methods were used to study the effects of added potassium fluoride on electrochemical behavior. The chemical state of magnesium alloy in the electroplating bath was analyzed by X-ray photoelectron spectroscopy. Adhesion of the copper electroplated layer was also tested. Due to the added potassium fluoride, a magnesium fluoride film was formed in the pyrophosphate copper bath. This fluoride film inhibits dissolution of Mg alloy and enables to electroplate copper directly on it. A dense copper layer was formed on the Mg alloy. Moreover, this copper layer has a good adhesion with Mg alloy substrate.

keyword : thin film, deposition, electrochemistry, scanning electron microscopy, SEM, magnesium

Salt bath nitriding, which has been developed recently by domestic company, is an emerging ecofriendly surface treatment. The salt bath nitriding is accompanied by the electrolysis process in the pretreatment step, and this whole processis called Pseudo-Electrolysised Salt bath Nitriding (PESN). The PESN creates only NH3 and non-toxic salts without harmful CN- or toxic gas such as that found in previous salt bath nitriding. In general, ion nitriding and gas nitriding create high hardness and a strong brittle white layer on the surface. However, the PESN shows a thin white and gray layer. The PESN was applied to the defense material, 3%Cr-Mo-V steel, to study the surface characteristics at 480℃, 530℃, and 580℃ for 4 hrs, 20 hrs, 40 hrs, and 60 hrs of nitriding time condition. As a result, the best nitriding layer was found at 530℃ for 40 hrs. If we improve corrosion resistance and nitriding layer depth, the PESN will be able to be applied to the defense industry parts.

keyword : alloys, coating, surface, wear, X-ray diffraction

The interfacial adhesion properties of enamel-coated, alloyed steels were in detail characterized by spectroscopic techniques. The surfaces of alloyed steels existed as oxidized states of Fe3O4. Therefore, the oxidized surfaces of the steels significantly interacted with the coated enamels for the adhesion. Ti-alloyed steel showed many micro-boundaries during thermal treatment and these micro-boundaries might cause the decline of the interfacial adhesion between enamel and steel. The depth profiles of enamel-coated, alloyed steels were investigated by GDS (glow discharge spectroscopy) and Ti component was found to be related to the interfacial adhesion between enamel and steel.

keyword : alloys, coating, interfaces

In order to develop the vacuum distillation process of magnesium alloy scrap, a fundamental study on the evaporation behavior of magnesium alloy (AM50) scrap melt was carried out. Melt temperature, pressure, reaction time, and initial specific surface area of melt were considered as experimental variables. The evaporation rate of magnesium increased with the increase of melt temperature and initial specific surface area of melt, and with the decrease of the pressure. The activation energy of magnesium evaporation reaction calculated by an Arrhenius plot decreased with the decrease of the pressure and with the increase of the initial specific surface area of melt. An empirical equation was derived for the evaporation rate of magnesium from AM50 alloy melt.

keyword : magnesium, vacuum, evaporation rate, scrap, recycling

The effect of various alloying elements and melt treatment on the microstructural control of Al-Sn metallic bearing alloy was investigated. The thickness of tin film crystallized around primary aluminum decreased with the addition of 5% Cu in Al-Sn alloy, with tin particles being reduced in size by intervening the Ostwald ripening. With the addition of Si in Al-10%Sn alloy, the tin particles were crystallized with eutectic silicon, resulting in uniform distribution of tin particles. With the addition of Cu and Si in Al-Sn alloy, both the tensile strength and yield strength increased, with the increasing rate of yield strength being less than that of tensile strength. Although the Al-10%Sn-7%Si alloy has similar tensile strength compared with Al-10%Sn-5%Cu, the former showed superior abrasion resistance, resulting from preventing the tin particles from movement to the abrasion surface.

keyword : Al-Sn, alloys, casting, wear, electron backscattering

In this work, high-k dielectric stacks of HfO2 and HfO2/Al2O3/HfO2 (HAH) were deposited on SiO2/ Si substrates by atomic layer deposition as charge trapping layers in charge trapping devices. The structural stability and the charge trapping characteristics of such stacks were investigated using Metal-Alumina- Hafnia-Oxide-Silicon (MAHOS) structure. The surface roughness of HfO2 was stable up to 11 nm with the insertion of 0.2 nm thick Al2O3. The effect of the thickness of the HAH stack and the thickness of intermediate Al2O3 on charge trapping characteristics were investigated for MAHOS structure under various gate bias pulse with duration of 100 ms. The threshold voltage shift after programming and erase showed that the memory window was increased with increasing bias on gate. However, the programming window was independent of the thickness of HAH charge trapping layers. When the thickness of Al2O3 insertion increased from 0.2 nm to 1 nm, the erase window was decreased without change in the programming window.

keyword : semiconductors, deposition, electrical properties, TEM, flash memory