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The changes in microstructure and mechanical properties of AZ31 alloy subjected hot-rolling process were investigated. The AZ31 plates fabricated by horizontal continuous casting process were prepared and have hot-rolled from 30 mm to 1 mm in thickness under different processing conditions. At the rolling temperature of 400℃, little surface and side crack was observed up to 20% reduction rate. As total reduction and reduction rate increase to more than 75% and 20% pass, respectively, Grains were more uniformly refined through overall thickness, and particularly lots of shear bands were appeared to be inclined at less than 20° along the rolling direction. Average grain size of less than 5 μm and tensile properties of YS ≥ 250 MPa, UTS ≥ 300 MPa and El. ≥ 13% were acquired for hot-rolled AZ31 sheets without post-heat treatment. Maximum intensity of (0002) pole figure was decreased with an increase in reduction rate, indicating the improvement of texture by means of high reduction rate.

keyword : magnesium alloys, hot-rolling, horizontal continuous casting, microstructure, texture

This study is concerned with effects of complex oxides on Charpy impact toughness of heat affected zone (HAZ) of API X80 linepipe steels. Three kinds of steels were fabricated by varying alloying elements such as Ti, Al, and Mg and hot-rolling conditions to form complex oxides, and their microstructures and Charpy impact properties were investigated. The number of complex oxides present in the steel containing excess Ti, Al, and Mg was twice larger than that in the conventional steels, while their size ranged from 1 to 3 μm in the three steels. After the HAZ simulation test, the steel containing a number of oxides contained about 20 vol.% of acicular ferrite in the simulated HAZ, together with bainitic ferrite and martensite, whereas the HAZ microstructure of the conventional steels consisted of bainitic ferrite and martensite with a small amount of acicular ferrite. This formation of acicular ferrite in the oxide-containing steel was associated with the nucleation of acicular ferrite at complex oxides, thereby leading to the great (five times or more) improvement of Charpy impact toughness over the conventional steels.

keyword : API X80 Linepipe steel, heat affected zone, complex oxides

Super austenitic stainless steels shows the high PRE (Pitting Resistance Equivalent) number and the good corrosion resistance. This work controlled the Co contents in Fe-31Cr-1.7Mo-27Ni-0.25N alloys to elucidate the effect of cobalt contents on the biocompatibility and corrosion resistance. Increasing Co contents, the hardness of the annealed alloys tends to be reduced. In aged alloys, cobalt decreased the increments of hardness by aging treatment. Cobalt decreased the critical pitting temperature (CPT) in 6% FeCl3 + 1% HCl solution, but improved the anodic polarization behavior in Hanks` balanced salt solution and artificial saliva solution. Repassivation rate in artificial body solutions was improved by increasing cobalt contents, but didn`t show the linear relationship to PRE number of the alloys. The experimental alloys showed the non-cytotoxicity because of its high corrosion resistance.

keyword : super austenitic stainless steel, cobalt, biocompatibility, pitting, anodic polarization, repassivation

Characteristics of etching and induced surface morphology variation by wet-etching of n-face ntype GaN were investigated using KOH solutions. It was observed that hexagonal pyramids were formed on the etched surface regardless of etching conditions. However, the size of the hexagonal pyramids was changed as the etching time and temperature increased, respectively. Initially, as the etching time and concentration of KOH solution increased, the hexagonal pyramid was observed to be dissociated into smaller pyramids. However, as the etching time increased further, the size of the hexagonal pyramids increased again, indicating that the etching of N-face n-type GaN by KOH solutions proceeded through the evolution of hexagonal pyramids, such as formation, dissociation and enlargement of pyramids. Furthermore, it was also observed that there is a correlation between the photoluminescence intensity of the etched surface and the value of rootmean- square roughness. The intensity of PL increased as the roughness value increased due to the enhancement of the extraction efficiency of the generated photons.

keyword : wet etch, n-face GaN, RMS roughness, KOH

The comparison of sintering behavior and mechanical properties of ultra-fine WC-10wt.%Co and WC-10wt.%Fe hard materials produced by high-frequency induction heated sintering (HFIHS) was accomplished using ultra fine powder of WC and binders(Co, Fe). The advantage of this process allows very quick densification to near theoretical density and prohibition of grain growth in nano-structured materials. Highly dense WC-10Co and WC-10Fe with a relative density of up to 99% could be obtained with simultaneous application of 60 MPa pressure and induced current within 1 minute without significant change in grain size. The hardness and fracture toughness of the dense WC-10Co and WC-10Fe composites produced by HFIHS were investigated.

keyword : rapid sintering, high-frequency induction heated sintering, wc-fe, wc-co, hard materials, hardness, fracture toughness

Solvent extraction reaction of cobalt by Alamine336 from strong hydrochloric acid solution was identified by analyzing the solvent extraction data reported in the literature. Analysis of the data by graphical method revealed that Alamine336 took part in the solvent extraction reaction as a monomer in the concentration ranges, [Co(II)] : 0.0169 - 0.102 M, [Alamine336] ; 0.02 - 1.75M, and [HCl ] : 5 - 10M. The following solvent extraction reaction and equilibrium constant was obtained from the experimental data by considering the activity coefficients of chemical species present in the aqueous phase. Co2++ 2Cl-+R3NHClorg = CoCl3 R3NHorg, Kex = 2.21 The distribution coefficients of cobalt predicted in this study agreed well with those reported in the literature.

keyword : CoCl2, HCl, Alamine336, solvent extraction reaction, equilibrium constant

The reductive precipitation of platinum and palladium in hydrochloric acid solution using hydrazine as a reducing agent was investigated. The reductive precipitation ratios of platinum and palladium increased when increasing the stoichiometric ratio for reducing agent, precipitation time, and pH. The precipitation ratio of platinum was much lower than that of palladium. This is the reason the reaction rate of PtCl6 2- → PtCl4 2- at the reduction reaction step of PtCl6 2- → PtCl4 2- → Pt is very slow. The purity of platinum precipitated was very affected by metallic impurities, while it was possible to precipitate the high purity palladium since the precipitation rate of palladium was relatively fast. At the pH of 1.3, the precipitation temperature of 25℃, and the addition amounts of the hydrazine of 10 and 1.75 times the stoichiometric ratio, the reductive precipitation ratios of platinum and palladium from their hydrochloric acid solutions containing 2,000 ppm were 98.5% and 99.9% in 30 min, respectively.

keyword : reductive precipitation, platinum, palladium, hydrochloric acid solution, metallic impurities

Gas turbine blades serviced for a period are usually repaired for reuse via "rejuvenation processes" including fluoride ion cleaning, brazing or welding, and recoating. Among these processes, the welding process is applied to rebuilt damaged parts of the blade in which welding materials being mostly Ni base superalloy are supplied in the form of powder or wire. When powder is used in the welding process, the uniform supply of powder is a very important factor for the uniformity of welding. According to our experience, the uniformity was very poor with the powder supply system only utilizing pressurized air flow. A new powder supply system was developed in which powder is supplied via air flow and simultaneously mechanically. The welding uniformity was much improved with this new system. In this study, the microstructure and mechanical properties of welded parts obtained from several kinds of powder using the new powder supply system were characterized.

keyword : Ni-superalloy, gas turbine repair, rejuvenation, welding

0.5 wt% Al doped ZnO thin films (AZO) were prepared on glass substrates using RF magnetron sputtering method. Thin films were grown at substrate temperature of 250℃, RF power of 75W, working pressure of 10 mTorr, by changing the O2/Ar pressure ratio from 0% to 16.7%. The effects of oxygen partial pressure during the deposition process on structural and optical properties of the films were investigated using XRD, SEM, AFM, EPMA and UV-visible spectroscopy. All the AZO thin films were grown as hexagonal wurtzite phase with the c-axis preferred out-of-plane orientation. The surface roughness and grain size of AZO films decreased with increasing oxygen ratio from 10.6 nm to 3.2 nm and 94.9 nm to 30.9 nm, respectively. On the other hand, the transmittance and band gap energy of the AZO films increased from 84.7% to 92.6% and 3.24 eV to 3.28 eV, respectively with increasing the O2/Ar pressure ratio.

keyword : AZO, thin film, Oxygen ratio, Transparent conducting oxide, TCO, sputtering

Hydrogen induced cracking (HIC) was phenomenologically studied in terms of the effect of nonmetallic inclusions and hot rolling process parameters. By comparing the level of non-metallic inclusions in two different kinds of commercial grade steels having different HIC resistance, the role of non-metallic inclusions in HIC occurrence was investigated. Change in inclusion morphology and distribution during hot rolling was also studied throughout slab, rolling at austenite recrystallization region (roughing mill; RM) and rolling at austenite non-recrystallization region (finish mill; FM). In addition, the contribution of RM and FM parameters to HIC was investigated from the standpoint of change in inclusion morphology during hot rolling processes. As a result, HIC was closely related to the separation of large complex inclusion during hot rolling process. Large complex inclusions originated from the improper Ca treatment, after which equilibrium composition of slag should have resulted in eutectoid composition. By controlling the equilibrium slag composition equivalent to eutectoid one, HIC resistance could be improved due to the reduced size of inclusions. In addition, change in reduction/pass in RM had an effect on HIC resistance of steels while that in FM did not. Increase in the reduction/pass in the latter stage of RM improved HIC resistance of steels by enhancing the void enclosure around inclusions.

keyword : Linepipe steel, hsla steel, hydrogen induced cracking, HIC, inclusion, hot rolling