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Vol.62, No.10, 787 ~ 796, 2024
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| Title |
| Enhanced Thermoelectric Performance of Bi0.5Sb1.5Te3 through Precise Pb Doping: Analysis Using the Single Parabolic Band Model |
| 강지원 Ji-won Kang , 황성미 Seong-mee Hwang , 김세윤 Se Yun Kim , 이창우 Changwoo Lee , 서원선 Won-seon Seo , 김상일 Sang-il Kim , 김현식 Hyun-sik Kim |
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| Abstract |
| This study investigates the thermoelectric properties of Pb-doped p-type Bi0.5Sb1.5Te3 alloys using the Single Parabolic Band (SPB) model, focusing on optimizing room-temperature performance. We systematically analyze the effects of Pb doping (0, 0.49, 0.65, 0.81, 0.97, and 1.3 at%) on key parameters including density-of-states effective mass (md*), non-degenerate mobility (μ0), weighted mobility (μW), and the thermoelectric quality factor (B-factor) at 323 K. The results reveal that md* reaches a maximum of 1.37 me at 0.97 at% Pb doping, representing a 22.25 % increase over the pristine sample. The highest μ0 of 234.5 ㎠ V-1 s-1 is achieved at 0.65 at% Pb, highlighting the complex relationship between doping and carrier mobility. Notably, 0.97 at% Pb doping optimizes thermoelectric performance, yielding the highest μW, power factor, and B-factor. This composition also minimizes lattice thermal conductivity (κl) by 44.93 % compared to the undoped sample, significantly reducing phonon heat conduction. The Callaway-von Baeyer model corroborates these findings, indicating maximized point defect scattering at 0.97 at% Pb. A theoretical peak figure-of-merit (zT) of 1.74 is thus predicted at this doping level, demonstrating a possible substantial enhancement in thermoelectric efficiency upon appropriate carrier concentration tuning. The observed trends in Seebeck coefficient, Hall carrier concentration, and Hall mobility with increasing Pb content provide insights into the underlying mechanisms of performance enhancement. This comprehensive study highlights the critical role of precise Pb doping in optimizing the thermoelectric properties of Bi0.5Sb1.5Te3 alloys for room-temperature applications and establishes a framework for future investigations into similar material systems. |
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| Key Words |
| thermoelectric, B-factor, weighted mobility, single parabolic band model, Callaway-von Baeyer model |
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