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Vol.61, No.12, 915 ~ 923, 2023
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| Title |
| Estimation of the Highest Thermoelectric Performance of the Bi-Doped SnTe at Room Temperature |
| 이준하 Joonha Lee , 박현진 Hyunjin Park , 김정연 Jeong-yeon Kim , 서원선 Won-seon Seo , 양희선 Heesun Yang , Umut Aydemir , 김세윤 Se Yun Kim , 신원호 Weon Ho Shin , 김현식 Hyun-sik Kim |
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| Abstract |
| SnTe has drawn much attention due to its Pb-free composition along with tunable electronic and lattice structures. However, its intrinsically high defect concentration and high lattice thermal conductivity (κl) have hindered its application in devices. Recently, Bi doping at Sn-sites in Sn1-xBixTe (x = 0.0 - 0.08) has been demonstrated to be effective in improving the thermoelectric performance (zT) of SnTe. Bi doping was particularly effective in improving the Seebeck coefficient in a wide range of temperature while suppressing its κl. However, the effect of Bi doping on electronic band structure of SnTe has not been studied. Here, we applied the Single Parabolic Band (SPB) model to the room temperature electronic transport properties measurements (Seebeck coefficient, electrical conductivity, Hall carrier concentration) and analyzed how electronic band parameters like the density-of-states effective mass (md *), non-degenerate mobility (μ0), weighted mobility (μw), and B-factor changes with a changing Bi doping content (x). As the x increases, the md * increases while μ0 decreases. As the μw depends both on md * and μ0, it peaks at x = 0.02. Lastly, the Bfactor is related to the ratio of μw to κl, due to significantly decreasing κl at high x, the B-factor also becomes the highest at x = 0.08. Based on the B-factor of x = 0.08 sample, the highest theoretical zT of 0.31 is predicted using the SPB model. This is approximately 2.2 times higher than the experimental zT (~0.139) reported in literature at 300 K. The SPB model also guides us that the highest theoretical zT of 0.31 can be achieved if its Hall carrier concentration is tuned to 9.06 × 1018 cm-3.
(Received 13 July, 2023; Accepted 6 September, 2023) |
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| Key Words |
| SnTe, Single Parabolic Band model, density-of-states effective mass, non-degenerate mobility, weighted mobility |
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