| Abstract |
| Cu-Sb-Se ternary chalcogenide compounds composed of earth-abundant low-toxicity elements are attracting attention as economical and ecofriendly semiconductors. Among them, permingeatite (Cu3SbSe4) is a potential thermoelectric material with high Seebeck coefficient and low lattice thermal conductivity. However, it is necessary to improve its thermoelectric properties through doping, as it has low electrical conductivity due to its low intrinsic carrier concentration. In this study, samples of Cu3Sb1-x-ySnxInySe4 (0.02 ≤ x ≤ 0.08 and 0.04 ≤ y ≤ 0.06) double-doped with In (group 13 element) and Sn (group 14 element) at the Sb (group 15 element) sites of permingeatite were synthesized and their thermoelectric performances were evaluated. All samples exhibited a single phase of permingeatite with tetragonal structure, and high relative densities of 97.4-98.9%. The lattice constants of the a- and c-axes were 0.5651-0.5654 and 1.1249-1.1257 nm, respectively, owing to the successful substitution of Sn and In at the Sb sites. As the doping concentrations of Sn and In increased, the carrier (hole) concentration increased. Thus, the Seebeck coefficient decreased, while the electrical and thermal conductivities increased. Sn doping was found to be more effective than In doping. Because Cu3Sb0.96-xSnxIn0.04Se4 exhibits higher Seebeck coefficients than Cu3Sb0.94-xSnxIn0.06Se4, larger power factors and higher dimensionless figures of merit (ZTs) were achieved for the Cu3Sb0.96-xSnxIn0.04Se4 specimens. Cu3Sb0.92Sn0.04In0.04Se4 achieved a maximum ZT of 0.59 at 623 K, based on its Seebeck coefficient of 161 μVK-1, electrical conductivity of 4.69 × 104 Sm-1, thermal conductivity of 0.77 Wm-1K-1, and power factor of 1.22 mWm-1K-2.
(Received 19 January, 2023; Accepted 27 February, 2023) |
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| Key Words |
| thermoelectric, permingeatite, double doping, mechanical alloying, hot pressing |
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