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Vol.57, No.9, 582 ~ 589, 2019
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| Title |
| Optimization of the CMP Process with Colloidal Silica Performance for Bulk AlN Single Crystal Substrate |
| Hyo Sang Kang , Joo Hyung Lee , Jae Hwa Park , Hee Ae Lee , Won Il Park , Seung Min Kang , Sung Chul Yi |
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| Abstract |
| Chemical mechanical polishing (CMP) of bulk AlN was performed with colloidal silica slurry at pH 9 for different times. The result shows that colloidal silica slurry at pH 9, which has the relatively high surface charge of -50.7 mV is most stable, and it was selected as chemically optimum condition in this study. The ultra-smooth surface was shown in CMP 90 min with the roughness average (Ra) value of 0.172 nm. It was demonstrated that the damaged layers including subsurface defects and micro scratches in the whole machining process were successfully removed and atomically flat surface can be shown. With increasing process time, the zeta potential and mean particle size of the colloidal silica decreased and increased by -35.07 mV and 143.4 nm, respectively. While the silica particles agglomerated and densely packed slurry particles were formed by mechanical shearing. These increased the Ra value above 0.5 nm of AlN substrate and generated additional surface damages. In terms of the surface chemistry, the carbon compounds and organic impurities adsorbed on the substrate during mechanical polishing (MP) can be removed and aluminum oxidehydroxide; AlOOH and Al(OH)3 were observed during the CMP. It was determined that the chemically polished AlN substrate was continuously hydrated with generating the AlOOH and Al(OH)3 on the surface.
(Received June 4, 2019; Accepted July 15, 2019) |
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| Key Words |
| aluminum nitride, chemical mechanical polishing, colloidal silica, material removal rate, surface chemistry, slurry agglomeration |
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