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Vol.48, No.1, 62 ~ 71, 2010
Title
Recovery of Nickel and Cobalt by a Hydrometallurgical Process from Nickel Laterite Ore with High Magnesium Content
이만승 Man Seung Lee , 김상배 Sang Bae Kim , 최영윤 Young Yun Choi , 채종귀 Jong Wee Chae
Abstract
Leaching and solvent extraction experiments have been performed to develop a hydrometallurgical process for the recovery of nickel and cobalt from nickel laterite ore with high magnesium content. Most of the nickel and magnesium in the laterite ore dissolved at leaching conditions of 80℃ and 100 g/L sulfuric acid concentration. while half of the cobalt and iron were leached at the same conditions. Solvent extraction experiments were carried out with D2EHPA and saponifed D2EHPA from a synthetic solution containing Ni, Co, and Mg. The extraction percentage of Co, Mg. and Ni by D2EHPA was very low in a pH range of 4.4 to 7.3. while the extraction percentage sharply increased by using saponified D2EHPA. The stripping percentage of the metals from the saponified D2EHPA increased with sulfuric acid concentration and reached 99.9% at 1 M H2SO4 solution.
Key Words
Ni Laterite ore, Leaching, solvent extraction, stripping D2EHPA
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