발간논문

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Vol.41, No.8, 457 ~ 466, 2003
Title
Effect of Oxygen on Phase Boundary in Dilute Nb Area of Zr-Nb Alloy
김윤선 Kim Yun Seon , 김현길 Kim Hyeon Gil , 홍순익 Hong Sun Ig , 정용환 Jeong Yong Hwan
Abstract
The phase boundary and Nb solubility of Zr-xNb binary alloys containing 2000 ppm oxygen were investigated by using DSC, metallography and TEM. To obtain the equilibrium phase, the alloys of Zr containing 0 to 10 wt.% Nb were annealed for a long time at different temperature. The phase transformation temperature from alpha to alpha+beta and alpha+beta to beta in the Zr containing 2000 ppm oxygen was analyzed at 980℃ and 1025℃. The phase transformation temperature of the Zr containing 2000 ppm oxygen was increased than that of the Zr having 700 ppm oxygen. The monotectoid temperature of the Zr-Nb alloys containing 2000 ppm oxygen was revealed at 585℃. From the analysis of precipitates using TEM equipped EDS, Nb-containing precipitates were observed on the Zr-0.2Nb alloy that annealed at monotectoid temperature. This means that the maximum Nb solubility in Zr-xNb binary alloy containing 2000 ppm oxygen would be lower than 0.2 wt.%.
Key Words
Sponge Zr, Zr-Nb, Alpha, Beta, Monotectoid, Microstructure, Precipitation
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