발간논문

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Vol.34, No.4, 535 ~ 540, 1996
Title
Research Paper - Environment - : A Study on the Oxidation Behavior of A356.2 Alloys
김동희Dong Hee Kim, 임성철Sung Chul Lim, 김정식Jung Sik Kim, 이창희Chang Hee Lee, 윤의박Eui Pak Yoon
Abstract
Experiments were performed by thermogravimetric(TG) technique for A356.2(Al-7Si-0.4Mg) aluminum alloy containing 0.4wt%Mg to examine the effect of magnesium on the oxidation kinetics in dry and moist air over the temperature range of 200∼550℃. The results of TG analysis showed that oxidation in moist air was much faster than in dry air at high temperatures above 525℃ while oxidation in both dry and moist air below 200℃ was stagnant. For the surface analysis of oxidation, the results of Auger electron spectroscopy(AES), X-ray diffraction patterns(XRD), analysis showed that only aluminum oxide was formed at relatively low temperature of 300℃ while the duplex film structure of Mg oxide/Al oxide/matrix was formed at high temperature of 550℃. MgO was a major constituent on the surface of oxide film, but the relative concentration of MgO decreased with increasing depth, while that of spinel, MgAl₂O₃ increased.
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