The Correlation of the Thermodynamic Properties and Phase Diagram of the System Cd - Pb
최순돈 Soon Don Choi
Abstract
A method of correlating with precision the thermodynamic properties and phase boundaries of the cadmium-lead system is described. For the liquid phase, the Krupkowski equation is used to correlate the enthalpy data of Kleppa, the excess free energy data of Zabdyr, and the eutectic point data of Hansen and Anderko. For the fcc (Pb) phase, a quasi-regular model is used. The calculated phase diagram of the cadmium-lead system using these formalisms agrees well with the experimental diagram.